Читать Review. Benzene on the basis of the three-electron bond. Theory of three-electron bond in the four works with brief comments (review). 2016. - Volodymyr Bezverkhniy

© Volodymyr Dmytrovych Bezverkhniy, 2017

© Vitaliy Volodymyrovich Bezverkhniy, перевод, 2017

ISBN 978-5-4483-6946-9

Создано в интеллектуальной издательской системе Ridero

I express my deep gratitude to my son, Bezverkhniy Vitaliy Volodymyrovich, for participation in the development of the theory (some parts as a co-author), and for his invaluable contribution to the English translation.

Abstract: Using the concept of three-electron bond we can represent the actual electron structure of benzene and other molecules, explain specificity of the aromatic bond and calculate the delocalization energy. Gives theoretical justification and experimental confirmation of existence of the three-electron bond.

It was shown, that functional relation y = a + b/x + c/x^>2 fully describes dependence of energy and multiplicity of chemical bond from bond distance.

Keywords: benzene, three-electron bond, semi-virtual particle, fermion, entangled quantum state, Interfering Universe.

Chemical bond has been always a basis of chemistry. Advancement of chemical science can be considered as evolution, development of concepts about chemical bond. Aromatic bond is fundamental basis of organic chemistry. Concept of three-electron bond in benzene molecule enable to explain specificity of aromatic bond. It also becomes apparent, why planar molecules with 6, 10 etc. electrons (according to Hückel rule 4n +2) must be aromatic, and planar molecules with 4, 8 etc. electrons cannot be aromatic by definition.

Description of chemical bond, that is given by quantum theory, especially in terms of method of molecular orbitals, is just a mathematical model. This model is an approximate representation of molecules and its bonds, whereas quantum-mechanical calculations of organic molecules require considerable simplifications and are extremely complicated.

Concept of three-electron bond and developed mathematical relations in this work are rather simple, illustrative and give exact results of different values (bond multiplicity, chemical bound energy, delocalization energy of benzene). One must clearly imagine, that three-electron bond is joint interaction of three electrons with relative spins, that results in new type of chemical bond (A • • • A (+ – +), A • • • B (+ – +)). This bond type, three-electron bond, makes possible to describe real molecules of organic and inorganic compounds without invoking virtual structures, which do not exist in real terms.